Magnesium metal is used
throughout our industry for alloying. Magnesium metal and its alloys are
explosive hazards; they are highly flammable in their pure form when molten or
in powder or ribbon form. Magnesium is capable of reducing water to
highly flammable hydrogen gas. Burning or molten magnesium metal
reacts violently with water. Here is a recent story that illustrates the
hazard of magnesium.
Firefighters
battled a magnesium fire for a second day at a factory in Japan during the week
of May 11, 2014.
Held
back by the intense heat from the burning magnesium, they couldn’t enter plant
until the following morning. The blaze was under control at around 4:30 p.m.,
but completely extinguishing it would take more time, firefighters said. The
fire had broken out at around 4:15 p.m. the day earlier.
They
were forced to rely on sand and special retardants because magnesium can
explode on contact with water. About 1,400 sq. meters of the two-story facility
was gutted, firefighters said.
The
magnesium processed at the plant is used to make computer components.
According
to the local Fire Department, the temperature of the surface of the first floor
ceiling was about 100 degrees as of Wednesday morning, while the air
temperature within the facility reached as high as 50 degrees. The first
firefighters on the scene used water on the blaze but stopped as soon as they
were informed about magnesium being processed at the facility.
One
plant worker was listed in serious condition and seven others suffered minor
injuries, the fire department said. The employee in serious condition is
reportedly a man in his 60s who suffered severe burns. The others injured are
six men ranging in age from their 20s to 40s and a woman in her 30s. More than
10 other workers were reportedly inside the factory when the fire started.
According to the police, workers said the fire started when a
spark from an operation using a soldering iron ignited some magnesium and
aluminum that were being processed.
The
processing work takes place on the facility’s first floor. Soon after the fire
broke out, the fire department issued a voluntary evacuation advisory for
residents within 100 meters of the plant. About 30 people were evacuated to
nearby public gymnasiums. The
local Government also alerted residents in adjacent areas to stay
indoors.
The
fire department warned that extinguishing the fire would continue for some
time, given that firefighters needed about 16 hours to control a blaze at another factory in May 2012.
The factory
is located in a residential area near the boundary between two large cities,
about 1 km a busy commuter train line.
A man
in his 70s who lives in the area said that after he heard a loud “boom,” his
house started shaking. “When I went outside (I saw) black smoke coming (from
the facility) and a few people in ripped clothes sitting (outside the factory),”
he said.
The
Aluminium Plant Safety Blog prays for a quick and full recovery for all of the
injured worker’s physical and mental injuries.
Because
the first responders were unaware of what the source of the fire was, the APSB
does not place blame on them pouring water onto the fire. Nevertheless, they are
lucky to be alive. Applying water to a magnesium/aluminium fire is never
recommended. There are numerous cases where firemen have been killed by
spraying water onto an aluminium or magnesium fire. Upon being made aware that magnesium
was fueling the fire they immediately stopped applying water onto it.
The
Aluminium Plant Safety Blog recommends that at least once a year all plants
invite local fire departments for a tour of your facility. Which the local fire
department can be made aware of the hazards in your facility. Most importantly
they can learn the location of the hazards as well as the location(s) of utility
shutoff valves (e.g., gas, electric, water, etc.). Answer these questions:
1.
Does your plant offer tours
to local fire departments on a regular basis?
2.
Does your plant have a
developed a detailed map (locating hazards, shutoff values, etc.) that has been
given to the local fire department?
If you
answered no on either question, your plant needs to reevaluate its emergency
management plan.
The
North American Die Casting Association (NADCA) has numerous great safety
presentations. Their website can be viewed here.
NADCA's excellent PowerPoint presentation titled "Fire Safety for
Magnesium Processing & Finishing Operations" it can be downloaded here.
Midsouth
Rescue Technologies has some useful information pertaining toward magnesium
fires. It can be viewed here.
When a
fire breaks out, do you have the appropriate Class D Fire Extinguisher? If
not, get one immediately!
Occupational
Safety Health Administration (OSHA) has information pertaining toward the
different types of fire extinguishers. It can be viewed here:
Finally the magazine
"Popular Science" post titled "Let Burning Metals Lie, There's
not much you can do to put a magnesium fire". The post talks about the
science behind a magnesium fire. The informative post can be viewed here.
Update.
The APSB is sadden to find out that one of the injured workers has succumbed to his injuries. While another worker remains in a coma. We pray for the family, friends, coworkers of the deceased worker as well as the injured worker in the coma.
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